Alkali Metal Cation versus Proton and Methyl Cation Affinities: Structure and Bonding Mechanism
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منابع مشابه
Alkali Metal Cation versus Proton and Methyl Cation Affinities: Structure and Bonding Mechanism
We have analyzed the structure and bonding of gas-phase Cl-X and [HCl-X](+) complexes for X(+)= H(+), CH3 (+), Li(+), and Na(+), using relativistic density functional theory (DFT). We wish to establish a quantitative trend in affinities of the anionic and neutral Lewis bases Cl(-) and HCl for the various cations. The Cl-X bond becomes longer and weaker along X(+) = H(+), CH3 (+), Li(+), and Na(...
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ژورنال
عنوان ژورنال: ChemistryOpen
سال: 2016
ISSN: 2191-1363
DOI: 10.1002/open.201500208